The Fiji-born wing, who has scored 46 tries in 66 Tests for the All Blacks, will link up with Bayonne following this year's World Cup in New Zealand.
Rokocoko, 27, has agreed a two-year deal with the option of a third year, moving to Europe from Auckland Blues.
And he becomes Bayonne's latest big-name signing for next season following their recruitment of All Blacks forwards Neemia Tialata and Sione Lauaki, plus Toulouse's France international wing Cedric Heymans.
"He is a passionate guy who is not coming here on holiday," Bayonne sporting director Christian Gajan told the club's official website.
Gilbert has released a new line of rugby cleats. The Gilbert Virtuo 8S is part of the exciting new product. Check it out.
The entire All Blacks apparel line has been updated for 2013/14. Check out the New Zealand All Blacks polo.
The Nike Tiempo is a solid rugby cleat and one of few styles still made from full-grain natural leather.
The Gilbert Blitz 8S rugby cleat is a great cleat at a great price of $69.99. Get a new pair of cleats today.
A cool looking all black rugby cleat with the high performance adidas is known for. Get in the Gear!
Wear the crest of the British and Irish Lions on your t-shirt. A great look for the summer.
$29.99
The All Blacks Performance t-shirt is black with hints of blue from the training jersey. Very Cool.
The New Zealand All Blacks training jersey for 2013/14. Get in the Gear!
The USA Rugby Pro Alternate rugby jersey is perfect for any fan of the Eagles. Get yours to wear during the summer Test matches.
The NEW All Blacks 2013/14 jersey has arrived at World Rugby Shop. Dare to wear the colors of the All Blacks.