Muliaina is included as one of seven changes to the All Blacks' starting line-up following the 37-17 win over France for his first appearance of the tournament, which is his third World Cup.
Muliaina replaces Corey Jane, who drops out of the matchday squad, with Israel Dagg moving from full-back to wing.
Kieran Read is in as head coach Graham Henry unites his first-choice back row, with the number eight joining Jerome Kaino and captain Richie McCaw, who is set to win his 101st cap.
It will be Read's World Cup debut and wing Zac Guildford is included for his maiden tournament appearance.
Read replaces Adam Thomson and Guildford comes in for Richard Kahui, respectively.
Keven Mealamu drops to the bench, with Andrew Hore coming in at hooker, lock Brad Thorne is rested, with Ali Williams starting in his place, and Sonny Bill Williams starts in place of Ma'a Nonu, who is rested.
Scrum-half Jimmy Cowan will win his 50th cap in place of Piri Weepu, who is named on the bench.
Team: M Muliaina, I Dagg, C Smith, SB Williams, Z Guildford, D Carter, J Cowan; T Woodcock, A Hore, O Franks, S Whitelock, A Williams, J Kaino, R McCaw (capt), K Read.
Replacements: K Mealamu, B Franks, B Thorn, A Boric, P Weepu, C Slade, I Toeava.
Gilbert has released a new line of rugby cleats. The Gilbert Virtuo 8S is part of the exciting new product. Check it out.
The entire All Blacks apparel line has been updated for 2013/14. Check out the New Zealand All Blacks polo.
The Nike Tiempo is a solid rugby cleat and one of few styles still made from full-grain natural leather.
The Gilbert Blitz 8S rugby cleat is a great cleat at a great price of $69.99. Get a new pair of cleats today.
A cool looking all black rugby cleat with the high performance adidas is known for. Get in the Gear!
Wear the crest of the British and Irish Lions on your t-shirt. A great look for the summer.
$29.99
The All Blacks Performance t-shirt is black with hints of blue from the training jersey. Very Cool.
The New Zealand All Blacks training jersey for 2013/14. Get in the Gear!
The USA Rugby Pro Alternate rugby jersey is perfect for any fan of the Eagles. Get yours to wear during the summer Test matches.
The NEW All Blacks 2013/14 jersey has arrived at World Rugby Shop. Dare to wear the colors of the All Blacks.